Murugavel, Ramaswamy ; Kuppuswamy, Subramaniam (2008) Water in organoaluminum chemistry! Three-in-one aluminophosphate clusters that incorporate boehmite repeating units Chemistry - A European Journal, 14 (13). pp. 3869-3873. ISSN 0947-6539
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/chem.20...
Related URL: http://dx.doi.org/10.1002/chem.200800320
Abstract
Mix and match! Slow introduction of water in the reaction between a monoaryl phosphate and an aluminum alkyl or Al2Cl6 leads to the formation of three-in-one clusters, which constitute aluminophosphate and aluminum hydroxide moieties within the same molecules (see graphic, C and H atoms not shown). Impeding the attack of water by kinetically stabilizing the aluminum alkyl leads to the isolation of a dimeric aluminophosphate, which throws mechanistic insights into the formation of larger clusters.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
Keywords: | Aluminum; Cluster Compounds; Hydrolysis; Phosphates; X-ray Diffraction; Zeolite Analogues |
ID Code: | 30414 |
Deposited On: | 23 Dec 2010 03:06 |
Last Modified: | 03 Mar 2011 07:00 |
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