Syntheses, spectroscopy and crystal structures of new group 4 metallasiloxanes

Voigt, Andreas ; Murugavel, Ramaswamy ; Roesky, Herbert W. ; Schmidt, Hans-Georg (1997) Syntheses, spectroscopy and crystal structures of new group 4 metallasiloxanes Journal of Molecular Structure, 436-437 . pp. 49-57. ISSN 0022-2860

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00222...

Related URL: http://dx.doi.org/10.1016/S0022-2860(97)00222-6

Abstract

The reactions of the organic-soluble (trimethylsilyl)arylaminosilanetriol RSi(OH)3 (R = (2,6-i-Pr2C6H3)NSiMe3) (1) with titanocene dichloride and zirconocene dichloride in dimethoxyethane as the solvent leads to the formation of acyclic and cyclic siloxanes [RSi(OH)2(OTiCp2Cl)] (2) and [RSi(OH)(OZrCp2)O]2 (3), respectively. The molecular structures of the new products 2 and 3 have been established by means of their analytical and spectral data. Further, in each case the solid-state structure of the compounds has been determined by single crystal X-ray diffraction studies. The EI mass spectral data reveal the presence of higher molecular weight compounds in the gas phase corresponding to the bicyclic or cubic structures of 2 and 3, respectively.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Silanetriol; Siloxanes; Metallasiloxanes; Titanocene and Zirconocene
ID Code:30408
Deposited On:23 Dec 2010 03:08
Last Modified:03 Mar 2011 09:45

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