Murugavel, Ramaswamy ; Banerjee, Subarna (2003) First alkaline earth metal 3-aminobenzoate (3-aba) complex: 1-D polymeric [Ca(3-aba)2(H2O)2]n assembly Inorganic Chemistry Communications, 6 (7). pp. 810-814. ISSN 1387-7003
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S13877...
Related URL: http://dx.doi.org/.1016/S1387-7003(03)00112-6
Abstract
The reaction of CaCO3 or CaCl2·2H2O with 3-abaH results in the formation of the first alkaline-earth metal complex of 3-abaH [Ca(3-aba)2(H2O)2]n (1) in good yield. The product has been characterized by elemental analysis, IR, UV-vis and 1H NMR spectral studies, TGA and single crystal X-ray diffraction studies. The molecular structure of 1 is made up of 1-D polymeric chains that are hydrogen-bonded to each other. The Ca2+ ion in 1 is surrounded by eight oxygen atoms in a distorted square-antiprismatic geometry.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Calcium; Aminobenzoate Complexes; Coordination Polymers; X-ray Structure |
| ID Code: | 30395 |
| Deposited On: | 23 Dec 2010 03:10 |
| Last Modified: | 17 May 2016 13:03 |
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