Voigt, Andreas ; Murugavel, Ramaswamy ; Montero, Mavis L. ; Wessel, Helge ; Liu, Feng-Quan ; Roesky, Herbert W. ; Uson, Isabel ; Albers, Thomas ; Parisini, Emilio (1997) Soluble molecular titanosilicates Angewandte Chemie International Edition, 36 (9). pp. 1001-1003. ISSN 1433-7851
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...
Related URL: http://dx.doi.org/10.1002/anie.199710011
Abstract
Titanosilicates with structural characteristics similar to those of many Ti-containing zeolites were synthesized from the reactions of (arylamino)silanetriol [RSi(OH)3] with organometallic titanium precursors [Cp∗TiCl3], TiCl4·2THF, and [Cp∗TiMe(μ-O)]3. The product of the reaction with [Cp∗TiCl3], 1, is a soluble molecular silicate in which formal TiO2 fragments are trapped inside. Cp∗ = C5Me5; R = (2,6-iPr2C6H3)NSiMe3.
Item Type: | Article |
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Source: | Copyright of this article belongs to John Wiley and Sons, Inc. |
Keywords: | Heterogeneous Catalysis; Metal Oxides; Silicon; Titanium; Zeolites |
ID Code: | 30390 |
Deposited On: | 22 Dec 2010 10:52 |
Last Modified: | 03 Mar 2011 09:59 |
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