Ismadji, S. ; Bhatia, S. K. (2003) Solubility of selected esters in supercritical carbon dioxide The Journal of Supercritical Fluids, 27 (1). pp. 1-11. ISSN 0896-8446
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S08968...
Related URL: http://dx.doi.org/10.1016/S0896-8446(02)00190-0
Abstract
The solubility of ethyl propionate, ethyl butyrate, and ethyl isovalerate in supercritical carbon dioxide was measured at temperature ranging from 308.15 to 333.15 K and pressure ranging from 85 to 195 bar. At the same temperature, the solubility of these compounds increases with pressure. The crossover pressure region was also observed in this study. The experimental data were correlated by the semi-empirical Chrastil equation and Peng-Robinson equation of state (EOS) using several mixing rules. The Peng-Robinson EOS gives better solubility prediction than the empirical Chrastil equation.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Solubility; Supercritical Co; Ethyl Propionate; Ethyl Butyrate; Ethyl Isovalerate |
| ID Code: | 3032 |
| Deposited On: | 09 Oct 2010 10:15 |
| Last Modified: | 17 May 2011 06:22 |
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