Synthesis and properties of some chromium(III) β-diketonate complexes

Mahendra, Kadidal N. ; Parashar, Gyanendra K. ; Mehrotra, Ram C. (1978) Synthesis and properties of some chromium(III) β-diketonate complexes Transition Metal Chemistry, 3 (1). pp. 130-133. ISSN 0340-4285

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Official URL: http://www.springerlink.com/content/k4327207p650k7...

Related URL: http://dx.doi.org/10.1007/BF01393527

Abstract

Equimolar quantities of CrCl3°3THF and β-diketones, β-dkH, react to yield CrCl2(β-dk) · 2THF and CrCl2(β-dk)·THF complexes in coordinating and noncoordinating solvents respectively. For 1:2 and 1:3 molar ratios of reactants, derivatives of general formulae CrCl(β-dk)2 and Cr(β-dk)3 (whereβ-dkH = acerylacetrrnc, benzoylacetonc and dibenzoylmethane) have been isolated. All complexes have been characterized by elemental analysis, molecular weights and by i.r. spectra.

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Deposited On:22 Dec 2010 09:59
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