Preparation, characterisation, and spectroscopic studies of homo- and heterobimetallic pinacolate derivatives of alkaline earth metals

Sharma, Malti ; Singh, Anirudh ; Mehrotra, Ram C. (2002) Preparation, characterisation, and spectroscopic studies of homo- and heterobimetallic pinacolate derivatives of alkaline earth metals Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 32 (7). pp. 1223-1233. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1081/SIM-120014299

Abstract

Reactions of insoluble metal glycolates of the type with Al(OPr-i)3 in 1:2 molar ratio in C6H6 afford hydrocabon-soluble heterobimetallic pinacolate derivatives . All of these derivatives have been characterized by elemental analyses, molecular weight measurements, and spectroscopic [IR, NMR (1H, 13C, 27Al)] studies.

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