Athar, T. ; Bohra, R. ; Mehrotra, R. C. (1989) Bimetallic alkoxides of tin(II), lead(II) and antimony(III): synthesis and characterization of [KSn(OR)3],[Sb(Sn(OR)3)3] and [Pb(Sb(OR)4)2] Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 19 (2). pp. 195-206. ISSN 1553-3174
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Related URL: http://dx.doi.org/10.1080/00945718908048062
Abstract
A few bimetallic alkoxides of the types [MSn(OR)3], [Sb(Sn(OR)3)3] and [Pb(Sb(OR)4)2] [M = Na, K, R = CH3, C2H7, n and i-C3H7, n and i-C4H9 and i-C5H11] have been prepared and characterized. These are generally coloured solids or viscous liquids. These are monomeric and covalent in nature and are hydrolytically unstable to atmospheric moisture. IR, 1H and 13C and 119Sn NMR studies suggest 3-coordination around tin in these derivatives.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30225 |
| Deposited On: | 22 Dec 2010 10:36 |
| Last Modified: | 07 Jun 2011 04:59 |
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