Ratnani, R. ; Srivastava, G. ; Mehrotra, R. C. (1990) Synthesis and characterization of dichlorodimethoxymolybdenum (V) 0,0'-dialky l(alkylene) dithiophosphate complexes Phosphorus, Sulfur, and Silicon and the Related Elements, 48 (1-4). pp. 245-249. ISSN 1042-6507
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Related URL: http://dx.doi.org/10.1080/10426509008045905
Abstract
Dichlorodimethoxymolybdenum(V) 0.0'-dialkyl dithiophosphates, MoCI2(OMe)2S2,P(OR)2 (where R = Et, Prn, Pri,Bui) and dichlorodimethoxymolybdenum (V), 0,0'-alkylene dithiophosphates, MoCI2(OMe)2S2POGO (where G = CH2CMe2-, -CMe2,CMe2-,-CHMeCHMe-) have been synthesized by the reactions of MoCI3 (OMe)2, with sodium (or ammonium) salts of the corresponding dithiophosphoric acids. These complexes have been characterized on the basis of elemental analyses, 31P NMR spectral data, magnetic studies and molecular weight determinations, which show their paramagnetic as well as dimeric nature. Based on these data, plausible structures containing hepta-coordinated molybdenum have been suggested for these compounds.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| Keywords: | Dialkyl (alkylene) Dithiophosphoric Acid Ligands; Molybdenum (V) Sulphur Derivatives; Phosphorus-31 NMR Spectra; Magnetic Susceptibilities |
| ID Code: | 30221 |
| Deposited On: | 22 Dec 2010 10:36 |
| Last Modified: | 07 Jun 2011 04:56 |
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