Mehrotra, R. C. ; Parashar, G. K. (1978) Synthesis, molecular weights and infrared spectra of mixed carboxylate complexes of titanium(IV) Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 8 (2). pp. 195-205. ISSN 1553-3174
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Related URL: http://dx.doi.org/10.1080/00945717808057404
Abstract
Mixed carboxylates of titanium (IV) with the general formula (o-C6H4O.COO)Ti(OPri)2 I, (o-C6O.COO)Ti(OPri)(OOCR) II and (o-C6H4OH.COO)Ti(OPri)(OOCR)2 III, (where R = C11H23, C15H31 and C21H43, have been synthesized and characterized. The intermolecular association in these compounds has been found to decrease in the order I > II > III. On the basis of their infrared spectra, the carboxylate groups of fatty acids have been shown to be unidentate, but that of salicylic acid appears to be bidentate in these complexes.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30210 |
| Deposited On: | 22 Dec 2010 10:38 |
| Last Modified: | 07 Jun 2011 06:48 |
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