Synthesis of β-ketoamine derivatives of aluminum

Mehrotra, R. C. ; Dayal, J. (1971) Synthesis of β-ketoamine derivatives of aluminum Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 1 (4). pp. 287-294. ISSN 1553-3174

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Related URL: http://dx.doi.org/10.1080/00945717108057273

Abstract

Aluminium isopropoxide reacts with β-ketoamines (CH3C(O)CHC(NHR)CH3, R = ethyl, n-propyl, n-butyl) in benzene to give the mono-, bis-, and tris- ketoamine complexes of aluminium (depending on the ratio of reactants) in a clean, high-yield reaction. The hydrolytically unstable products are relatively volatile, soluble and monomeric in benzene. The infrared spectra of the complexes are reported.

Item Type:Article
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Deposited On:22 Dec 2010 10:39
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