Mahendra, K. N. ; Mehrotra, R. C. (1990) Preparation and reactions of chromium(III)alkoxides Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 20 (7). pp. 963-973. ISSN 1553-3174
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Official URL: http://www.informaworld.com/smpp/content~db=all~co...
Related URL: http://dx.doi.org/10.1080/00945719008048188
Abstract
Reactions of CrCl3·3THF with lithium alkoxides in 1:3 molar ratio in the respective primary alcohols yield insoluble trialkoxides, Cr(OR)3 (where R = Me, Et, Bu-n). The corresponding reactions with isopropyl and tertiary butyl alcohols, however, yield hydrolysed products only. We have been able to synthesize the isopropoxide and t. butoxide also by alternative routes. All the alkoxides have been characterized by physico-chemical methods and attempts have been made to study their alcoholysis reactions.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30207 |
| Deposited On: | 22 Dec 2010 10:39 |
| Last Modified: | 07 Jun 2011 04:57 |
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