Goel, S. C. ; Mehrotra, S. K. ; Mehrotra, R. C. (1977) Synthesis and properties of some metal cinnamoxides Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 7 (6). pp. 519-530. ISSN 1553-3174
Full text not available from this repository.
Official URL: http://www.informaworld.com/smpp/content~db=all~co...
Related URL: http://dx.doi.org/10.1080/00945717708069732
Abstract
Three cinnamyl borates, B(OCH2-CH = CH-C6H5)3 (I), [B(OCH2-CH=CH-C6H5)2]2O (II) and [OB(OCH2-CH=CH-C6H5)]3 (III) have been synthesized by heating cinnamyl alcohol with boric oxide under vacuo. (I) was also synthesized by alcoholysis of ethyl borate with cinnamyl alcohol. The reactions of aluminium isopropoxide with cinnamyl alcohol in different stoichiometric ratios yield A1[OCH(CH3)2]3-n (OCH2-CH=CH-C6H5)n (where n = 1,2 or 3). Tetracinnamoxides of titanium and germanium and pentacinnamoxides of niobium and tantalum as well as di-n-butyltin dicinnamoxide and tri-n-butyltin monocinnamoxide were also synthesized by alcoholysis reactions. IR and PMR spectral properties of these new derivatives have been discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 30203 |
| Deposited On: | 22 Dec 2010 10:39 |
| Last Modified: | 07 Jun 2011 06:52 |
Repository Staff Only: item control page
