Synthesis of alkoxysilanes by insertion reactions of halosilanes with cyclic ethers

Mehrotra, R. C. ; Bajaj, P. (1970) Synthesis of alkoxysilanes by insertion reactions of halosilanes with cyclic ethers Journal of Organometallic Chemistry, 22 (1). pp. 37-40. ISSN 0022-328X

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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)83074-0

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)83074-0

Abstract

A number of new chloro-substituted alkoxysilanes have been synthesised by the interaction of RnSiCl4-n (R = H, CH3, C2H5, C6H5 and CH=CH2 and n = 1, 2, 3) with epichlorohydrin (2,3-epoxypropyl chloride) and ethyl and butyl glycidyl ether (ethyl and butyl 2,3-epoxypropyl ether). The silicon atom becomes attached through oxygen to the secondary carbon atom.

Item Type:Article
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ID Code:30175
Deposited On:22 Dec 2010 10:46
Last Modified:08 Jun 2011 04:41

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