Double alkoxides of niobium and tantalum with aluminium and gallium

Govil, S. ; Kapoor, P. N. ; Mehrotra, R. C. (1975) Double alkoxides of niobium and tantalum with aluminium and gallium Inorganica Chimica Acta, 15 . pp. 43-46. ISSN 0020-1693

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Official URL: http://dx.doi.org/10.1016/S0020-1693(00)93909-4

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)93909-4

Abstract

Double isopropoxides of niobium and tantalum with aluminium and gallium with general formulae, [MM' (OPri)8] and [MM'2(OPri)11] have been prepared by refluxing their isopropoxides in isopropanol in molar ratio 1:1 and 1:2. These are soluble in organic solvents and are distilled under reduced pressure. The mono derivatives are dimeric with considerable dissociation, while bis-products are monomeric in refluxing benzene. IR and in some cases NMR spectra have been reported and discussed.

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