Bajaj, P. ; Mehrotra, R. C. ; Maire, J. C. ; Ouaki, R. (1972) Insertion reactions of organochlorosilanes with cyclic ethers Journal of Organometallic Chemistry, 40 (2). pp. 301-309. ISSN 0022-328X
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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)93368-0
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)93368-0
Abstract
Phenyl glycidyl ether and allyl glycidyl ether (3-phenoxy- and 3-allyloxy-1,2-epoxypropane) cause fission of the silicon---chlorine bonds in a number of alkylchlorosilanes to form chloro-substituted alkoxysilanes. Relative reactivities of cyclic ethers with chlorosilanes have been discussed. Structures of the adducts are suggested on the basis of their IR and proton magnetic resonance spectra.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30161 |
| Deposited On: | 22 Dec 2010 10:49 |
| Last Modified: | 08 Jun 2011 04:35 |
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