Sukhani, D. ; Gupta, V. D. ; Mehrotra, R. C. (1967) Thiolysis of alkyltin alkoxides and oxides Journal of Organometallic Chemistry, 7 (1). pp. 85-90. ISSN 0022-328X
Full text not available from this repository.
Official URL: http://dx.doi.org/10.1016/S0022-328X(00)90829-5
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)90829-5
Abstract
Dibutyltin diethoxide was found to interchange its ethoxy groups readily with thiols forming Bu2Sn(SR)2. These thiolates can also be synthesized by refluxing the crude Bu2SnO with thiols in the presence of benzene. Molecular weight determinations showed them monomeric. Some of these higher homologues can be prepared by displacement reactions with higher thiols. The reaction of dipropanethiodibutylstannane with ethanol is very slow even in the presence of catalyst.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30153 |
| Deposited On: | 22 Dec 2010 10:50 |
| Last Modified: | 08 Jun 2011 04:48 |
Repository Staff Only: item control page
