Puri, D. M. ; Pande, K. C. ; Mehrotra, R. C. (1962) Derivatives of titanium with compounds having bidentate ligands: IV. Chloride acetylacetonates of titanium Journal of the Less Common Metals, 4 (6). pp. 481-486. ISSN 0022-5088
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Official URL: http://dx.doi.org/10.1016/0022-5088(62)90035-8
Related URL: http://dx.doi.org/10.1016/0022-5088(62)90035-8
Abstract
The preparation of titanium dichloride diacetylacetone (TiCl2(acac)2) from titanium tetrachloride and titanium dichloride dialkoxide is described. It has been shown that the compound can be obtained by the reaction between titanium dialkoxide diacetylacetone and hydrogen chloride, whereas it is converted into the alkoxide derivative by the reaction with alcohol in presence of anhydrous ammonia. These reactions together with low conductivities in nitrobenzene confirm the simple monomeric formulation TiCl2(acac)2. The preparation of titanium trichloride monoacetylacetone has been described and its reactions and those of the dichloride derivative, with alcohols and acids have been studied.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30129 |
| Deposited On: | 22 Dec 2010 10:54 |
| Last Modified: | 08 Jun 2011 05:14 |
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