Mehrotra, S. K. ; Srivastava, G. ; Mehrotra, R. C. (1974) Stannoboroxanes: II. Synthesis and reactions of tris(trialkyltin) borates Journal of Organometallic Chemistry, 65 (3). pp. 361-366. ISSN 0022-328X
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Official URL: http://dx.doi.org/10.1016/S0022-328X(00)82270-6
Related URL: http://dx.doi.org/10.1016/S0022-328X(00)82270-6
Abstract
Tris(trialkyltin) borates B(OSnR3)3 (R = Me, Et, Pr, Bu, i-Bu and Ph) have been prepared by esterification of boric acid with trialkyltin hydroxide or bis(trialkyltin) oxide. These reacted with boric anhydride to give the corresponding trialkyltin metaborates (R3SnOBO)3. Reactions of tris(tributyltin) borate with hydrogen chloride, acetyl chloride, acetic acid, acetic anhydride, phenol, butanethiol, thiophenol and isopropyl acetate have been studied. The infrared spectra of these compounds are discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30111 |
| Deposited On: | 23 Dec 2010 03:11 |
| Last Modified: | 07 Jun 2011 07:08 |
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