Reactions of tin tetraacetate with sulphur ligands

Mehrotra, R. C. ; Srivastava, G. ; Vasanta, E. N. (1981) Reactions of tin tetraacetate with sulphur ligands Inorganica Chimica Acta, 47 . pp. 125-130. ISSN 0020-1693

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00201...

Related URL: http://dx.doi.org/10.1016/S0020-1693(00)89317-2

Abstract

Reactions of tin tetraacetate with thiols (n-C4H9SH and n-C6H13SH) dithiols [HS(CH2)NSH; N = 2,3,4 and 6], thioglycol [HS(CH2)2OH], thiocarboxylic acids (CH3COSH, C2H5COSH, C6H5COSH) and mercapto carboxylic acids (HSCH2COOH, HS(CH2)2COOH, and HSC6H4-o-COOH) have been carried out in chloroform or toluene (with the azeotropic removal of the liberated acetic acid) in various molar ratios. These reactions are very facile, yielding various types of compounds, containing Sn---S linkages. The new compounds, which are generally crystalline with sharp melting points, have been characterized by elemental analysis and IR as well as PMR spectral study.

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