Nag, Purnima ; Bohra, Rakesh ; Mehrotra, Ram C. ; Ratnani, Raju (2002) Chemistry of oxomolybdenum (V) and (VI) complexes incorporating oxygen, nitrogen and/or sulfur donor atoms. Part 1. Synthesis and characterization of [Mo2O3L4(LH = HSCH2CH2CO2H, HSCH2CO2Me or HSCH2CH2CO2Me) and [MoO2L'2] (L'H = HOC6H4NH2, HOCH2C6H4NH2,HOC6H4CHO or HOC10H8N) Transition Metal Chemistry, 27 (3). pp. 321-325. ISSN 0340-4285
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Official URL: http://www.springerlink.com/content/tb0ru1ay3lhqxw...
Related URL: http://dx.doi.org/10.1023/A:1014845702933
Abstract
Reactions of an acidified aqueous solution of Na2MoO4 · 2H2O with 3-mercaptopropionic acid, 2-mercaptomethylethanoate and 3-mercaptomethyl propanate yield blue oxo-bridged MoV complexes of the type [Mo2O3L4], whereas corresponding reactions with 2-aminophenol, 2-aminobenzyl alcohol, salicylaldehyde and 2-methyl-8-hydroxyquinoline, yield yellow dioxomolybdenum(VI) complexes, [MoO2L' 2]. All these coloured solids are sparingly soluble, even in coordinating solvents. They have been characterized by elemental and spectroscopic analysis.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Springer-Verlag. |
| ID Code: | 30100 |
| Deposited On: | 23 Dec 2010 03:13 |
| Last Modified: | 07 Jun 2011 04:34 |
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