Kapoor, R. N. ; Mehrotra, R. C. (1959) Organic compounds of zirconium. Part VI. Reactions of zirconium tetrachloride and isopropoxide with fatty acids Journal of the Chemical Society, 76 . pp. 422-426. ISSN 0368-1769
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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1959...
Related URL: http://dx.doi.org/10.1039/JR9590000422
Abstract
Fatty acids with zirconium tetrachloride give tetracarboxylates directly. With zirconium isopropoxide only oxygen- bridged compounds of the type (R·CO2)3Zr·O·Zr(CO2R)3 are obtained. By studying the latter reaction stepwise, we find that it is straightforward to the dicarboxylate stage, after which side reactions occur. A mechanism is suggested.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 30094 |
| Deposited On: | 23 Dec 2010 03:15 |
| Last Modified: | 08 Jun 2011 05:20 |
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