Structural chemistry of the alkoxides. Part I. Amyloxides of silicon, titanium, and zirconium

Bradley, D. C. ; Mehrotra, R. C. ; Wardlaw, W. (1952) Structural chemistry of the alkoxides. Part I. Amyloxides of silicon, titanium, and zirconium Journal of the Chemical Society, 376 . pp. 2027-2032. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1952...

Related URL: http://dx.doi.org/10.1039/JR9520002027

Abstract

The isomeric amyloxides M(OC2H11)4 of titanium and zirconium have been prepared by alcoholysis. Boiling points(under reduced pressure) and molecular weights of these compounds and of n-butyl and neopentyl ortho-silicates have been measured. The influence of branching of the amyl group on the physical properties of these compounds id diecussed.

Item Type:Article
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