Misra, S. N. ; Misra, T. N. ; Mehrotra, R. C. (1965) Organic compounds of lanthanide elements-III: alcoholates of lanthanum and cerium (III) chlorides Journal of Inorganic and Nuclear Chemistry, 27 (1). pp. 105-113. ISSN 0022-1902
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...
Related URL: http://dx.doi.org/10.1016/0022-1902(65)80198-1
Abstract
The reactions of alcohols (methanol, ethanol, propanols, butanols etc.) with anhydrous lanthanum and cerium (III) chlorides have been investigated and a large number of new compounds with the general formula MCl3·3ROH have been isolated. When lanthanum and cerium (III) chloride monohydrates were allowed to react with alcohols, dialcoholates with the formula MCl3·H2O·2ROH were isolated. The synthesis of higher alcoholates from the lower derivatives was also successfully achieved by the use of alcohol interchange technique. Some physico-chemical properties (pyrolysis, molecular weight, conductivity and spectra) of these alcoholate derivatives were also studied.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30056 |
| Deposited On: | 23 Dec 2010 03:25 |
| Last Modified: | 08 Jun 2011 04:54 |
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