Shah, A. ; Singh, A. ; Mehrotra, R. C. (1986) Syntheses, characterization and adduct formation of chloride-2,4,6-trimethylphenoxide derivatives of titanium and zirconium Polyhedron, 5 (7). pp. 1285-1290. ISSN 0277-5387
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S02775...
Related URL: http://dx.doi.org/10.1016/S0277-5387(00)83473-7
Abstract
Chloride phenoxides of type MCl4-n(OAr')n (where M = Ti or Zr; n = 1, 2 or 3) have been prepared by the interaction of the metal chlorides with 2,4,6-trimethylphenol (Ar'OH). The mixed chloride phenoxides showed considerable reactivity as Lewis acids towards bases, resulting in addition complexes of general formula MCl4-n(OAr')nL2 (where L = primary or tertiary aromatic amines, or oxygen- or phosphorus-containing bases). These complexes have been characterized by IR and the 1H NMR studies, conductivity measurements, molecular weight measurements (in the case of soluble products), thermogravimetric and mass spectral studies.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 30051 |
| Deposited On: | 23 Dec 2010 03:38 |
| Last Modified: | 07 Jun 2011 06:04 |
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