Synthesis of novel termetallic isopropoxides

Abstract

Novel termetallic isopropoxides are reported which may be represented by the general formulae: [(PrⁱO)₃M(μ-OPrⁱ)₂Be(μ-OPrⁱ )₂Al(OPrⁱ)₂], [(PrⁱO)₂M(μ-OPrⁱ)₂Be(μ-OPrⁱ )₂Al(OPrⁱ)₂]₂ [where M = Ti(IV), Zr(IV) and Hf(IV)] and [(PrⁱO)₄M(μ-OPrⁱ) ₂Be(μ-OPrⁱ)₂Al(OPrⁱ )₂] [where M = Nb(V) and Ta(V)]. Attempts to synthesize derivatives with the general formula, [(PrⁱO)₇M₂ (μ-OPrⁱ)₂Be(μ-OPrⁱ)₂Al (OPrⁱ)₂] [where M = Ti(IV), Zr(IV) or Hf(IV)], were unsuccessful and in all such cases a mixture of M(OPrⁱ)₄ and [(PrⁱO)₃ M(μ-OPrⁱ)₂Be(μ-OPrⁱ)₂Al (OPrⁱ)₂] was obtained. All these derivatives are soluble in common organic solvents and with the exception of titanium(IV) derivatives, they can be volatilised without noticeable disproportionation. These products have been characterized by elemental analyses, molecular weights, IR, ¹H NMR and (in representative cases) mass spectral studies also.