Organic derivatives of germanium: I. Synthesis and reactions of dialkoxydi-n-Butylgermanes

Mathur, S. ; Chandra, G. ; Rai, A. K. ; Mehrotra, R. C. (1965) Organic derivatives of germanium: I. Synthesis and reactions of dialkoxydi-n-Butylgermanes Journal of Organometallic Chemistry, 4 (4). pp. 294-301. ISSN 0022-328X

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-328X(00)88836-1

Abstract

The preparation of a number of new di-n-butyldialkoxygermanes, Bu2Ge(OR)2, with R = CH3, C2H5, iso-C3H7, n-C4H9, sec-C4H9, iso-C4H9, tert-C4H9, tert-C5H11 or sec-C5H11 has been described, and their hydrolyses have been studied. Di-n-butylgermanium sulphide and di-n-butylgermanium bromide derivatives have been synthesized for the first time by the reactions of the alkoxides with hydrogen sulphide and acetyl bromide respectively.

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