Kumara Swamy, K. C. ; Day, Roberta O. ; Holmesa, Robert R. (1995) A new structural form of tin in a cubic cluster Phosphorus, Sulfur, and Silicon and the Related Elements, 99 (1-4). pp. 65-68. ISSN 1042-6507
Full text not available from this repository.
Official URL: http://www.informaworld.com/smpp/content~db=all~co...
Related URL: http://dx.doi.org/10.1080/10426509508031337
Abstract
We have reported new forms of tin comprised of oligomeric oxotin carboxylates that are based on the compositions [R'Sn(O)O2CR]61-5 and [(R'Sn(O)O2CR)2-R'Sn(O2CR)3]2.2-5 These have "drum" and "ladder" structures, respectively. We also reported the oxygen-capped cluster, [(n-BuSn(OH)O2PPh2)3O]-[Ph2PO2],6 which has tin in a partial cubic array surrounded by chelating phosphinate groups. In all of these forms, tin generally is octahedrally coordinated. One useful synthetic route for their formation employs the interaction of an alkyl or aryl stannoic acid with either a carboxylic acid or a phosphorus-containing acid.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Ltd. |
| ID Code: | 29593 |
| Deposited On: | 20 Dec 2010 07:59 |
| Last Modified: | 07 Jun 2011 06:21 |
Repository Staff Only: item control page
