Allylation of p-ketoaldehydes and functionalized imines by diallyltin dibromide: formation of skipped and conjugated dienes

Kumaraswamy, Sudha ; Nagabrahmanandachari, S. ; Kumara Swamy, K. C. (1996) Allylation of p-ketoaldehydes and functionalized imines by diallyltin dibromide: formation of skipped and conjugated dienes Synthetic Communications, 26 (4). pp. 729-744. ISSN 0039-7911

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Related URL: http://dx.doi.org/10.1080/00397919608003673

Abstract

Diallyltin dibromide reacts with β-keto-aldehydes possessing no aromatic side groups and with (hydroxy) aryl imines to afford the expected homoallyl alcohols or amines respectively. With β-ketoaldehydes having aromatic side groups, skipped or conjugated dienes are obtained depending on whether or not an aqueous work up procedure is used.

Item Type:	Article
Source:	Copyright of this article belongs to Taylor and Francis Ltd.
ID Code:	29592
Deposited On:	20 Dec 2010 07:59
Last Modified:	17 May 2016 12:25

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