A route, via tetraquinane, to the 5-8-5 carbocyclic nucleus of fusicoccins and ophiobolins

Mehta, Goverdhan ; Krishnamurthy, Nacharaju (1986) A route, via tetraquinane, to the 5-8-5 carbocyclic nucleus of fusicoccins and ophiobolins Journal of the Chemical Society, Chemical Communications . pp. 1319-1321. ISSN 0022-4936

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Official URL: http://www.rsc.org/publishing/journals/article.asp...

Related URL: http://dx.doi.org/10.1039/C39860001319

Abstract

Short, stereoselective syntheses of dicyclopenta[a,d]cyclo-octane-based diones (14) and (+)-(22)via a 5-5-5-5→5-8-5 strategy are reported; our approach constitutes an effective methodology for constructing fusicoccane and ophiobolane-type natural products.

Item Type:Article
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ID Code:29343
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