Mehta, Goverdhan ; Hari Krishna Reddy, S. ; Padma, S. (1991) Synthetic studies towards prismanes: exploratory efforts en route to [7]-prismane homo- and secologues Tetrahedron, 47 (37). pp. 7821-7836. ISSN 0040-4020
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Official URL: http://dx.doi.org/10.1016/S0040-4020(01)81938-4
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)81938-4
Abstract
Novel heptacyclic triones 8 and 9 have been synthesised. A series of probing experiments on the heptacyclic ketones 3, 8 and 9, in quest for [7]-prismane homo- and secologues are described. Synthesis of novel polyhedranes 23-25 through thermal 2+2-cycloreversion of 3, 8 and 17, respectively, has been achieved. Our results point to the need for devising de novo strategy for the creation of higher prismanic frameworks.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | [7]-Prismane; Heptacyclic Trione; Cycloreversion; Ti+3 Reduction; 2+2-Photocycloaddition |
| ID Code: | 29309 |
| Deposited On: | 17 Dec 2010 08:14 |
| Last Modified: | 17 Dec 2010 08:14 |
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