π-Facial stereoselectivities in Diels-Alder cycloadditions to a dissymmetric cyclohexa-1,3-diene moiety in a novel, caged polycyclic framework

Mehta, Goverdhan ; Padma, S. ; Hari Krishna Reddy, S. ; Nethaji, Munirathinam (1994) π-Facial stereoselectivities in Diels-Alder cycloadditions to a dissymmetric cyclohexa-1,3-diene moiety in a novel, caged polycyclic framework Journal of the Chemical Society, Perkin Transactions 1 . pp. 2049-2050. ISSN 0300-922X

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Official URL: http://www.rsc.org/publishing/journals/article.asp...

Related URL: http://dx.doi.org/10.1039/P19940002049

Abstract

Novel polycyclic 1,3-dienes 4 and 5 have been synthesised and shown to undergo Diels-Alder cycloadditions exclusively from the carbonyl face. Steric environment seems to be predominantly responsible for the observed stereochemistry.

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