Modulation of π-facial selectivities in nucleophilic additions to 7-norbornenones

Mehta, Goverdhan ; Khan, Faiz Ahmed (1992) Modulation of π-facial selectivities in nucleophilic additions to 7-norbornenones Tetrahedron Letters, 33 (21). pp. 3065-3068. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)79601-8

Abstract

The pronounced syn-face selectivity exhibited by 7-norbornenone in hydride reduction is dramatically altered (reversed) by the remote electron withdrawing substituents at the C2,C3-endo -position. The syn-face selectivity shown by 7-norbornenones in hydride reduction is dramatically altered by the remote endo-substituent.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:7-Norbornenone; NaBH4 Reduction; π-face-selectivity
ID Code:29258
Deposited On:17 Dec 2010 08:19
Last Modified:16 Jul 2012 07:53

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