Accelerating effect of a remote cationic center on the cope rearrangement. Evidence of σ -participation by a norbornane C-C bond in a novel tetracyclic framework

Mehta, Goverdhan ; Padma, S. (1988) Accelerating effect of a remote cationic center on the cope rearrangement. Evidence of σ -participation by a norbornane C-C bond in a novel tetracyclic framework Journal of Organic Chemistry, 53 (20). pp. 4890-4892. ISSN 0022-3263

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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo00255a050

Related URL: http://dx.doi.org/10.1021/jo00255a050

Abstract

The first observation of accelaration of [3,3]- sigmatropic (Cope) rearrangement, by a remote cationic center, in a novel tetracyclic framework embodying a norbornyl moiety, is described.

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ID Code:29254
Deposited On:17 Dec 2010 08:19
Last Modified:17 Dec 2010 08:19

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