Novel cationic rearrangements of the [3.3.3]propellane system: application to the total synthesis of decarboxyquadrone

Mehta, Goverdhan ; Pramod, Kakumanu ; Subrahmanyam, Duvvuri (1986) Novel cationic rearrangements of the [3.3.3]propellane system: application to the total synthesis of decarboxyquadrone Journal of the Chemical Society, Chemical Communications (3). pp. 247-248. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1986...

Related URL: http://dx.doi.org/10.1039/C39860000247

Abstract

The first carbonium ion rearrangement of the [3.3.3]propellane ring system to the tricyclo[4.3.2.01,5]undecane and tricyclo[6.3.0.01,5]undecane skeletons has been observed and extended to the total synthesis of the biologically active compound decarboxyquadrone.

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