Synthetic studies towards crinipellins: construction of the functionalised C20-tetraquinane carbon framework through cationic enone-olefin cyclisation stratagem

Mehta, Goverdhan ; Srinivas Rao, K. ; Sreenivas Reddy, M. (1988) Synthetic studies towards crinipellins: construction of the functionalised C20-tetraquinane carbon framework through cationic enone-olefin cyclisation stratagem Tetrahedron Letters, 29 (39). pp. 5025-5028. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)80670-X

Abstract

A synthesis of 14-epi-crinipellin skeleton, adequately and appropriately functionalised, from a readily available triquinane precursor is described. In an approach to crinipellin A 1 , properly funtionalised C20-tetraquinane 21 has been synthesised from the readily available enone acetal 6.

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