Polycyclic rearrangements. A novel, carbonium ion mediated, bicyclo (4.2.0) octa-2,4-diene→1,3,5-cyclooctatriene isomerisation in a propellane framework

Mehta, Goverdhan ; Singh, Vishwakarma ; Srikrishna, A. ; Stanley Cameron, T. ; Chan, Christine (1979) Polycyclic rearrangements. A novel, carbonium ion mediated, bicyclo (4.2.0) octa-2,4-diene→1,3,5-cyclooctatriene isomerisation in a propellane framework Tetrahedron Letters, 20 (47). pp. 4595-4598. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)86659-4

Abstract

A serendipitious cationic rearrangement of hexacyclic propellane 9 to its strained fluxional isomer, the bridged 1,3,5-cyclooctatriene 10 is described.

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