Mehta, Goverdhan ; Roya, Subhrangsu ; Davis, Rohan A. (2008) On the stereostructures of (+)-eupenoxide and (-)-3',4'-dihydrophomoxide: a caveat on the spectral comparisons of oxygenated cyclohexenoids Tetrahedron Letters, 49 (35). pp. 5162-5164. ISSN 0040-4039
Full text not available from this repository.
Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2008.06.076
Abstract
The structural ambiguity surrounding the structure of eupenoxide has been clarified and the absolute configuration of this natural product has been assigned. It is firmly established that 'eupenoxide' recently reported by Liu et al. is in fact a new natural product, (-)-3',4'-dihydrophomoxide. The NMR spectra of these polyoxygenated cyclohexenoids exhibit subtle solvent, concentration, and temperature dependent variations, and due caution should be exercised when making spectral comparisons for structural assignments.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 29180 |
| Deposited On: | 18 Dec 2010 05:31 |
| Last Modified: | 18 Dec 2010 05:31 |
Repository Staff Only: item control page
