Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames

Mehta, Goverdhan ; Hari Krishna Reddy, S. ; Pattabhi, Vasantha ; Bhanumathi, S. ; Pramanik, Animesh ; Chandrasekhar, Jayaraman (1993) Stereoelectronic control of Cope rearrangement energetics through remote double bonds in novel, rigid polycyclic frames Journal of the Chemical Society, Perkin Transactions 1 . pp. 1539-1541. ISSN 0300-922X

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Official URL: http://www.rsc.org/publishing/journals/article.asp...

Related URL: http://dx.doi.org/10.1039/P19930001539

Abstract

The presence and orientation of remote double bonds are shown to completely alter the shapes of Cope rearrangement energy profiles in a heptacyclic system.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:29176
Deposited On:18 Dec 2010 05:31
Last Modified:13 Jul 2012 14:16

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