Mehta, Goverdhan ; Acharyulu, P. V. R. ; Reddy, K. Subba ; Umarye, Jayant D. (1997) Elaboration of S-(-)-α-pinene into functionalized bicyclo[4.2.1]nonane framework of mediterraneols Synlett, 1997 (10). pp. 1161-1162. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-1997-985
Abstract
A two-carbon ring expansion of (-)- α -pinene 1 to bicyclo[5.1.1]nonane system (+)-12 and 1,2-cationic rearrangement provides an entry into a functionalized bicyclo[4.2.1]nonane derivative, representing the carbocyclic skeleton, present in the novel marine diterpenes, mediterraneols.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers Inc. |
| Keywords: | "push-pull" Cyclopropane Fragmentation; Two-carbon Ring Expansion; Bicyclo[4.2. 1.]nonane; Marine Natural Products |
| ID Code: | 29157 |
| Deposited On: | 18 Dec 2010 05:32 |
| Last Modified: | 18 Dec 2010 05:32 |
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