Mehta, Goverdhan ; Gagliardini, Vanessa ; Schaefer, Carsten ; Gleiter, Rolf (2003) Thiabowls: synthesis, molecular structure and the solid state architecture of tetrathia-[4]-peristylane Tetrahedron Letters, 44 (52). pp. 9313-9316. ISSN 0040-4039
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Official URL: http://dx.doi.org/10.1016/j.tetlet.2003.10.038
Related URL: http://dx.doi.org/10.1016/j.tetlet.2003.10.038
Abstract
Synthesis of tetrathia-[4]-peristylane, the first thiabowl, from the dimer of cyclooctatetraene has been accomplished. The X-ray crystal structure of the tetrathiabowl indicates significant departure from the expected C4v symmetry and in the solid state it exhibits a multi-columnar arrangement and a novel 'self-inclusion' phenomenon, directed by a network of S...S and CH...S interactions.
| Item Type: | Article |
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| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Cyclic Thioethers; Intermolecular Interactions; Oxygen-sulfur Exchange |
| ID Code: | 29089 |
| Deposited On: | 18 Dec 2010 05:37 |
| Last Modified: | 17 May 2016 12:03 |
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