Enantioselective synthesis of epi-(+)-Sch 642305: observation of an interesting diastereoselection during RCM

Mehta, Goverdhan ; Shinde, Harish M. (2005) Enantioselective synthesis of epi-(+)-Sch 642305: observation of an interesting diastereoselection during RCM Tetrahedron Letters, 46 (39). pp. 6633-6636. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.07.152

Abstract

In an approach towards the enantioselective total synthesis of the novel bioactive natural product Sch 642305, an unusual diastereoselection during the key RCM reaction, resulted in the synthesis of the 11-epi-isomer of Sch 642305.

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ID Code:29024
Deposited On:18 Dec 2010 05:41
Last Modified:17 May 2016 12:00

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