Mehta, Goverdhan ; Umarye, Jayant D. (2001) Total synthesis of the bicyclo[6.3.0]undecane-based sesquiterpene (±)-asterisca-3(15),6-diene. Revision of the relative stereochemistry of the natural product Tetrahedron Letters, 42 (45). pp. 8101-8104. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(01)01779-8
Abstract
The first total synthesis of the novel bicyclic sesquiterpene hydrocarbon asterisca-3(15),6-diene is reported. As a consequence, the natural product is shown to possess structure 4 with a trans-5,8 ring fusion and not the previously assigned cis-asterisca-3(15),6-diene 3.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
Keywords: | Terpenes; Polyquinanes; Cyclooctanes; Wittig Reaction; Stereochemistry |
ID Code: | 29019 |
Deposited On: | 18 Dec 2010 05:42 |
Last Modified: | 17 May 2016 12:00 |
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