Mehta, Goverdhan ; Umarye, Jayant D. (2003) Studies towards the total synthesis of novel dolabellane-type diterpenoids: construction of the 5,11-fused bicyclic framework Tetrahedron Letters, 44 (39). pp. 7285-7289. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01873-2
Abstract
An oxy-Cope protocol has been grafted on to a previously crafted hydroazulenic system to provide a facile entry into the 5,11-fused bicyclic skeleton present in the novel neodolabellane diterpenoids. Formation of a novel tricyclic diterpenoid framework, generated through a transannular cyclization in the 11-membered ring present in the neodolabellane skeleton and embodying a bridged cycloheptatriene moiety, has also been encountered.
Item Type: | Article |
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Source: | Copyright of this article belongs to Elsevier Science. |
ID Code: | 29004 |
Deposited On: | 18 Dec 2010 05:43 |
Last Modified: | 17 May 2016 11:59 |
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