The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in π-facial selectivity in nucleophilic additions

Mehta, Goverdhan ; Singh, S. Robindro ; Gagliardini, Vanessa ; Priyakumar, U. Deva ; Sastry, G. Narahari (2001) The bicyclo[2.1.1]hexan-2-one system: a new probe for the experimental and computational study of electronic effects in π-facial selectivity in nucleophilic additions Tetrahedron Letters, 42 (48). pp. 8527-8530. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)01818-4

Abstract

The remotely substituted 5-exo-bicyclo[2.1.1]hexan-2-one system is introduced as a new probe to study long range electronic effects on π -face selectivity during hydride reduction and a systematic computational study demonstrates good predictability at the semi-empirical level.

Item Type:	Article
Source:	Copyright of this article belongs to Elsevier Science.
ID Code:	28980
Deposited On:	18 Dec 2010 05:44
Last Modified:	17 May 2016 11:58

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