A general, ring closure metathesis based enantiospecific approach to polyfunctional eudesmane, eremophilane and agarofuran sesquiterpenoids

Mehta, Goverdhan ; Senthil Kumaran, R. (2003) A general, ring closure metathesis based enantiospecific approach to polyfunctional eudesmane, eremophilane and agarofuran sesquiterpenoids Tetrahedron Letters, 44 (37). pp. 7055-7059. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(03)01757-X

Abstract

An enantiospecific and stereo- and functional group diversity oriented approach to eudesmane, eremophilane and agarofuran sesquiterpenoids from (-)-carvone has been devised. RCM has been employed as the key reaction to generate the highly functionalized eudesmane framework. Further elaboration of the eudesmane framework to agarofurans and biogenetic-type rearrangement to eremophilanes is outlined.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:28973
Deposited On:18 Dec 2010 05:45
Last Modified:17 May 2016 11:58

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