Mehta, Goverdhan ; Gagliardini, Vanessa ; Schaefer, Carsten ; Gleiter, Rolf (2004) Thiabowls: synthesis, molecular structure, and novel supramolecular architecture of trithia-[3]-peristylane Organic Letters, 6 (10). pp. 1617-1620. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol049507v
Related URL: http://dx.doi.org/10.1021/ol049507v
Abstract
A synthesis of trithia-[3]-peristylane, C6H6S3, a novel C3v symmetric thiabowl, from the exotic hydrocarbon bullvalene has been accomplished. The X-ray crystal structure of this trithiabowl displays an unprecedented supramolecular architecture in the solid state with 12 CH···S interactions involving all of its six hydrogen atoms and the two lone pairs on each of the three sulfur atoms.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 28969 |
| Deposited On: | 18 Dec 2010 05:45 |
| Last Modified: | 18 Dec 2010 05:45 |
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