Mehta, Goverdhan ; Khan, Faiz Ahmed ; Ananda Lakshmi, K. (1992) Modification of π-face selectivity of 7-norbornenones during reduction in β-cyclodextrin and solid state Tetrahedron Letters, 33 (51). pp. 7977-7980. ISSN 0040-4039
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4039(00)74793-9
Abstract
Electronically/electrostatically dictated face-selection in endo-substituted 7-norbornenones can be altered/reversed by means of host-guest interaction with β-CD. Reversal in face-selectivity is also observed in the reduction of 5,6-endo ,endo -substituted 7-norbornenone 2a in solid state.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | π-face Selectivity; β-cyclodextrin; NaBH4 Reduction Solid-state Reaction |
| ID Code: | 28947 |
| Deposited On: | 18 Dec 2010 05:46 |
| Last Modified: | 16 Jul 2012 07:54 |
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