Synthetic studies towards complex diterpenoids. Part 19. Total synthesis of (±)-deoxofaveline, (±)-faveline methyl ether and ( ±)-faveline

Ghosh, Ajit K. ; Mukhopadhyay, Chhanda ; Ghatak, Usha Ranjan (1994) Synthetic studies towards complex diterpenoids. Part 19. Total synthesis of (±)-deoxofaveline, (±)-faveline methyl ether and ( ±)-faveline Journal of the Chemical Society, Perkin Transactions 1 . pp. 327-332. ISSN 0300-922X

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Official URL: http://www.rsc.org/publishing/journals/article.asp...

Related URL: http://dx.doi.org/10.1039/P19940000327

Abstract

Simple and efficient syntheses have been developed for the cytotoxic dinorditerpenoids, (±)-deoxofaveline 1, (±)-faveline methyl ether 2 and (±)-faveline 3, having a hexahydrodibenzo[a,d]cycloheptene ring system, through the enolizable tricyclic ketone mixture 12 and 13, prepared from the easily accessible 2-arylethyl-3,3-dimethylcyclohexanone 7.

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