Highly regioselective 8-endo-aryl radical cyclisation: a new synthetic route to decahydrodibenzo-[a,d]- and -[a,e]-cyclooctenols

Ghosh, Keya ; Ghosh, Ajit K. ; Ghatak, Usha Ranjan (1994) Highly regioselective 8-endo-aryl radical cyclisation: a new synthetic route to decahydrodibenzo-[a,d]- and -[a,e]-cyclooctenols Journal of the Chemical Society, Chemical Communications (5). pp. 629-630. ISSN 0022-4936

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1994...

Related URL: http://dx.doi.org/10.1039/C39940000629

Abstract

A highly regioselective 8-endo-trig-aryl radical cyclisation of the vinylcyclohexanols 2a-c and allylcyclohexanols 6a-c with tri-n-butyltin hydride provides decahydrodibenzo-[a,e]- and -[a,d]-cyclooctenols 3a-c and 7a-c respectively, in moderate to good yields.

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